土工基础 ›› 2022, Vol. 36 ›› Issue (6): 980-984.

• 测试技术 • 上一篇    下一篇

土样浸出液中氯离子含量测定的不确定度评定

杨怡昱,施 虹,董继庆,谭 英,李 涛   

  1. (云南设计院集团勘察院有限公司,昆明 650000)
  • 收稿日期:2021-05-25 修回日期:2021-06-11 出版日期:2022-12-31 发布日期:2022-12-28
  • 作者简介:杨怡昱(1994-),女,助理工程师,硕士研究生,研究方向为岩土工程,环境污染治理。

Evaluation of the Uncertainty in Determining the Chloride Content in the Leached Liquid from Soil Samples

YANG Yiyu, SHI Hong, DONG Jiqing, TAN Ying, LI Tao   

  1. (Geotechnical Investigation Co. Ltd., Yunnan Design Institute Group, Kunming 650000)
  • Received:2021-05-25 Revised:2021-06-11 Online:2022-12-31 Published:2022-12-28

摘要: 针对黏土、粉质黏土和粉土三种不同种类土壤浸出液中氯离子含量在实际检测过程中可能引入的不确定度来源进行了分析和量化。依据标准氯离子浓度测定方法,对结果进行不确定度评定。结果表明,氯离子含量测量值为124.25 mg·kg-1的黏土试样,其扩展不确定度为0.075 mg·kg-1;氯离子含量测量值为193.48 mg·kg-1的黏土试样,其扩展不确定度为0.050 mg·kg-1;氯离子含量测量值为81.65 mg·kg-1的黏土试样,其扩展不确定度为0.129 mg·kg-1。同时,不同种类土样所有不确定度分量影响因素相同,贡献最大的为滴定土样浸出液消耗硝酸银体积引入的不确定度,其次为样品重复性测定引入的不确定度;取土样浸出液体积引入的不确定度影响最小。

关键词: 黏土, 粉质黏土, 粉土, 土样浸出液, 氯离子含量, 影响因素, 不确定度

Abstract: The uncertainty in determination the chloride content in the leached liquid from clay, silty clay and silty soil samples is analyzed and quantified in this paper. The chloride content determination method in “Standard for geotechnical testing method” (GB/T 50123-2019) is used to evaluate the uncertainty. The results showed that the expanded uncertainty of the clay soil extract sample with the chloride content of 124.25 mg/kg was 0.075 mg/kg, the silty clay soil extract sample with the chloride content of 81.65 mg/kg was 0.05 mg/kg and the silt soil extract sample with chloride content of 81.65 mg/kg was 0.075 mg/kg. Meanwhile, factors that influence all uncertainty components of different soil samples are the same. The most contribution of the uncertainty was the volume of the silver nitrate in titration. Then, is the uncertainty from the induced repeatability of the measurement and is followed by the volume of the leached liquid from the soil samples.

Key words: Clay, Silty Clay, Silt Soils, Leached Liquid from Samples, Chloride Content, Influencing Factors, Uncertainty

中图分类号: